2-(1-Adamantyl)-4-bromoanisole at 123 K

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2-(1-Adamant­yl)-4-bromo­anisole at 123 K

IN THE TITLE COMPOUND [SYSTEMATIC NAME: 2-(1-adamantyl)-4-bromo-1--methoxy-benzene], C(17)H(21)BrO, two weak intra-molecular C-H⋯O hydrogen bonds influence the mol-ecular conformation. The crystal packing exhibits C-H⋯π inter-actions, with a relatively short inter-molecular C⋯Cg contact of 3.568 (5) Å, where Cg is the centroid of the benzene ring. The crystal studied exhibited inversion twinning.

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1-Acetyl-5,6-dimethoxy­indoline at 123 K

In the title compound, C(12)H(15)NO(3), all C, N and O atoms lie in a mirror plane. An intramolecular C-H⋯O hydrogen bond is present.

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(E)-Methyl N′-(4-bromo­benzyl­idene)­hydrazinecarboxyl­ate at 123 K

The title compound, C(9)H(9)BrN(2)O(2), crystallizes with two independent but essentially identical mol-ecules in the asymmetric unit. Each mol-ecule adopts a trans configuration with respect to the C=N bond. In one of the mol-ecules, the dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 24.9 (2)°, and that in the other mol-ecule is 16.1 (2)°. The mol-ecules are ...

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Ethyl N′-[(E)-4-hydroxy­benzyl­idene]hydrazinecarboxyl­ate at 123 K

The mol-ecule of the title compound, C(10)H(12)N(2)O(3), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxyl-ate plane is 14.6 (1)°. Mol-ecules are linked into a three-dimensional network by O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, and by C-H⋯π inter-actions.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808016772